The Design Museum is a museum in Kensington, next to Holland Park, which covers product, industrial, graphic, fashion and architectural design. There is also a nice cafe on the 1st floor with beautiful views of the park.
The best thing about any charity shop is that you never know what you are going to find. I have a well tested route around London that includes all of my favourite charity shops. This Oxfam has a great selection of books and often turns up some interesting clothes too.