The best thing about any charity shop is that you never know what you are going to find. I have a well tested route around London that includes all of my favourite charity shops. This Oxfam has a great selection of books and often turns up some interesting clothes too.
The best place for a glass of wine*. It's the perfect balance – not too formal, not too informal either. Food is consistently good. Lamb's Conduit Street is a little oasis in the midst of Bloomsbury. (*slightly overpriced)
East london spot with a bit of everything, food during the day and cocktails, music and cinema during the night. Few nice places around like E5 bakery, Netil 360 rooftop, and Mare Street Market