The Greenwich Observatory with its green laser beam can transfigure any night sky. If you decide to cross the Thames via the foot tunnel, make sure you look out for the green ray. You can be on one side of the meridian in a minute, and cross to the other side on the next, without even realising it.
A great place to start the day if you are in South London is Federation Coffee in Brixton Village. The food is great and so is the coffee. This is a very chilled place where you can get both and indoor and outdoor experience (even though the whole place is under the Village roof).