Need some clean air or just a time-out? Kew Gardens is a short train ride away from the city centre but is provides you with space, greenery and and a small holiday for the lungs. The garden contain tropical glasshouses and interesting architecture, so it is a treat for both body and mind.
The second coffee shop has to be Kaffeine. Having only recently come across this one, I was certainly impressed and they may even have the best coffee I've had, since a short stay in Portland, Oregon.
The Party Superstore was/is my absolute favourite London shop until it was bizarrely attacked and gutted during the summer London riots. They have been since adopted as a concession by the local Debenhams but you can still savour the full delights of the products and nonsense on line.