If you want a peaceful day out of the busy city, Highgate doesn't really feel like London. The cemetery is interesting and peaceful, there's a tour of the old half which is definitely worth the money. Karl Marx, among others are buried there.
Maybe an obvious choice, but the Barbican is always good. My favourite space in there is the curve gallery, last time I went was for Cory Arcangel's 'Beat the Champ'. I love the architecture, although not many people do. I think it was voted 'London's ugliest building' in 2003.
This uninspiring sounding place is a disused railway line that runs along the roofline from Finsbury Park to Highgate. A great place to excerise and escape.