Not the most exciting place inside, but a lovely rooftop area which not all that many people seem to know about, 2 mins walk from Old St station. If it’s packed then The Red Lion is just up the road.
The walk along the South Bank from Westminster to Tower Bridge will take you past a plethora or interesting sights and cultural hotspots. There's always something interesting going on too.
If you want a peaceful day out of the busy city, Highgate doesn't really feel like London. The cemetery is interesting and peaceful, there's a tour of the old half which is definitely worth the money. Karl Marx, among others are buried there.