My favorite place on Bedford Avenue, this bookstore has both new and used titles. If you're patient and look close enough, you can usually find a book that's worth more than they're asking. Not to mention their stellar selection of magazine titles. Good for design, art, photography, sociology, fiction, and everything in between.
For brunch, the classic dish to get is the Feijoada, but the benny is also solid (and i don't recommend a benny lightly)—you can also ask for ham and spinach together (my favorite). For dinner you can also get the same thing, or the Moqueca (shrimp stew) is incredible. Pro-tip: if you're there for breakfast on a weekday, ask for a egg and cheese (add bacon or ham or avocado) on a croissant. Not on the menu—sounds basic, tastes amazing.
Having the experience of owning and running a coral reef aquarium (and frequenting this particular shop about once a week) - I was sad to hear it closed it's doors. Their reef display tank was always amazing. These pictures were taken from PetCo at Union Square (I also used to go there for my saltwater needs).